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91.
In this paper, we present a thermomechanical framework which makes use of the internal variable theory of thermodynamics for damage-coupled finite viscoplasticity with nonlinear isotropic hardening. Damage evolution, being an irreversible process, generates heat. In addition to its direct effect on material's strength and stiffness, it causes deterioration of the heat conduction. The formulation, following the footsteps of Simó and Miehe (1992), introduces inelastic entropy as an additional state variable. Given a temperature dependent damage dissipation potential, we show that the evolution of inelastic entropy assumes a split form relating to plastic and damage parts, respectively. The solution of the thermomechanical problem is based on the so-called isothermal split. This allows the use of the model in 2D and 3D example problems involving geometrical imperfection triggered necking in an axisymmetric bar and thermally triggered necking of a 3D rectangular bar. 相似文献
92.
《Journal of computational science》2014,5(4):568-575
Mechanisms for the decomposition reaction of ethylamine, CH3CH2NH2, were investigated using ab initio, DFT, and RRKM calculations. Optimized geometries of reactants, transition states, intermediates, and products were determined at HF, MP2, and B3LYP levels of theory using the 6-31G(d) and 6-31+G(d) basis sets. Single point energies were also determined at G3MP2B3 and G3B3 levels of theory. Thermodynamic properties, activation energies, enthalpies and Gibbs energies of activation were calculated for each reaction pathway investigated. Intrinsic reaction coordinate (IRC) analysis was performed to characterize the transition states on the potential energy surface. The conformational change and planarity of the ethylamine moiety along with the twist angle of the amino group about the CN axis are examined. Four pathways for the decomposition reaction of ethylamine were studied. All pathways involve a 1,2-elimination reaction and 1,3-proton shift to produce ethene, ethanimine, ethenamine, and methanimine. All pathways are single-step mechanisms. Elimination of the NH3 dominates the decomposition behavior up to 1200 K whereas after this temperature, secession of the C–N gradually holds more importance. While pathways signifying departures of NH3 and NH2 exhibit pressure-dependent behavior, branching ratios for these two channels are generally not influenced by variation in pressure higher than the atmospheric pressure. 相似文献
93.
A four-dimensional hyperchaotic system with five parameters is proposed. Its dynamical properties such as dissipativity, equilibrium points, Lyapunov exponent, Lyapunov dimension, bifurcation diagrams and Poincare maps are analyzed theoretically and numerically. Theoretical analyses and simulation tests indicate that the new system's dynamics behavior can be periodic attractor, chaotic attractor and hyperchaotic attractor as the parameter varies. Finally, the circuit of this new hyperchaotic system is designed and realized by Multisim software. The simulation results confirm that the chaotic system is different from the existing chaotic systems and is a novel hyperchaotic system. The system is recommendable for many engineering applications such as information processing, cryptology, secure communications, etc. 相似文献
94.
The Aharonov-Bohm effect (ABE) for steady magnetic fields is a well known phenomenon. However, if the current in the infinite solenoid that creates the magnetic field is time-dependent, that is in the presence of both magnetic and electric fields, there is no agreement whether the effect would be present. In this note, we try to investigate time varying ABE by a direct calculation in a set-up with a weak time dependent magnetic field. We find that the electric field arising out of the time-varying magnetic field in the path of the electrons does not enter the action integral but only changes the path of the electron from the source to the slits and then on to the detector. We find a frequency dependent AB phase shift. At low frequencies the result smoothly approaches the one for a constant field as the frequency tends towards zero. On the other hand, for high frequencies such that the AB-phase induced in the path of the wave packet oscillates rapidly, the net effect will be very small which is borne out by our results. 相似文献
95.
Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions. 相似文献
96.
Nonlinear filter generators are commonly used as keystream generators in stream ciphers. A nonlinear filter generator utilizes a nonlinear filtering function to combine the outputs of a linear feedback shift register (LFSR) to improve the linear complexity of keystream sequences. However, the LFSR-based stream ciphers are still potentially vulnerable to algebraic attacks that recover the key from some keystream bits. Although the known algebraic attacks only require polynomial time complexity of computations, all have their own constraints. This paper uses the linearization of nonlinear filter generators to cryptanalyze LFSR-based stream ciphers. Such a method works for any nonlinear filter generators. Viewing a nonlinear filter generator as a Boolean network that evolves as an automaton through Boolean functions, we first give its linearization representation. Compared to the linearization representation in Limniotis et al. (2008), this representation requires lower spatial complexity of computations in most cases. Based on the representation, the key recoverability is analyzed via the observability of Boolean networks. An algorithm for key recovery is given as well. Compared to the exhaustive search to recover the key, using this linearization representation requires lower time complexity of computations, though it leads to exponential time complexity. 相似文献
97.
Military, navigation and concealed weapon detection need different imaging modalities such as visible and infrared to monitor a targeted scene. These modalities provide complementary information. For better situation awareness, complementary information of these images has to be integrated into a single image. Image fusion is the process of integrating complementary source information into a composite image. In this paper, we propose a new image fusion method based on saliency detection and two-scale image decomposition. This method is beneficial because the visual saliency extraction process introduced in this paper can highlight the saliency information of source images very well. A new weight map construction process based on visual saliency is proposed. This process is able to integrate the visually significant information of source images into the fused image. In contrast to most of the multi-scale image fusion techniques, proposed technique uses only two-scale image decomposition. So it is fast and efficient. Our method is tested on several image pairs and is evaluated qualitatively by visual inspection and quantitatively using objective fusion metrics. Outcomes of the proposed method are compared with the state-of-art multi-scale fusion techniques. Results reveal that the proposed method performance is comparable or superior to the existing methods. 相似文献
98.
On the long‐range relativistic effects in the 15N NMR chemical shifts of halogenated azines 下载免费PDF全文
Dmitry O. Samultsev Yury Yu. Rusakov Leonid B. Krivdin 《Magnetic resonance in chemistry : MRC》2017,55(11):990-995
Long‐range β‐ and γ‐relativistic effects of halogens in 15N NMR chemical shifts of 20 halogenated azines (pyridines, pyrimidines, pyrazines, and 1,3,5‐triazines) are shown to be unessential for fluoro‐, chloro‐, and bromo‐derivatives (1–2 ppm in average). However, for iodocontaining compounds, β‐ and γ‐relativistic effects are important contributors to the accuracy of the 15N calculation. Taking into account long‐range relativistic effects slightly improves the agreement of calculation with experiment. Thus, mean average errors (MAE) of 15N NMR chemical shifts of the title compounds calculated at the non‐relativistic and full 4‐component relativistic levels in gas phase are accordingly 7.8 and 5.5 ppm for the range of about 150 ppm. Taking into account solvent effects within the polarizable continuum model scheme marginally improves agreement of computational results with experiment decreasing MAEs from 7.8 to 7.4 ppm and from 5.5 to 5.3 ppm at the non‐relativistic and relativistic levels, respectively. The best result (MAE: 5.3 ppm) is achieved at the 4‐component relativistic level using Keal and Tozer's KT3 functional used in combination with Dyall's relativistic basis set dyall.av3z with taking into account solvent effects within the polarizable continuum solvation model. The long‐range relativistic effects play a major role (of up to dozen of parts per million) in 15N NMR chemical shifts of halogenated nitrogen‐containing heterocycles, which is especially crucial for iodine derivatives. This effect should apparently be taken into account for practical purposes. 相似文献
99.
交通事故的时空热点分析 总被引:1,自引:0,他引:1
针对目前交通事故分析中时空维度分离的不足,以H市2013―2015年的交通事故数据为研究对象,根据自组织神经网络、平行坐标系、时空颜色矩阵和时空网络核密度估计、热点分析法,分别从行政区划以及道路网络上进行交通事故的时空特征分析,从宏观和微观角度揭示交通事故的时空热点区域。结果表明,整体来说,在空间上,H市交通事故热点区域4个街道高于8个镇,呈明显的“两带一中心”分布,即硖许线与101省道形成的带状区域和市政府所在的行政中心区域;时间上,早、晚高峰时段最为严重,夜晚较为轻微,呈明显的区域特征分布,即工业办公区热点出现在早高峰时段,生活住宅区热点出现在晚高峰时段,商业消费区热点出现在夜晚时段。 相似文献
100.
《偏微分方程通讯》2013,38(11-12):2513-2525
ABSTRACT The Hopf map from minimal surfaces in H 3 to holomorphic quadratic differentials on H 2 is considered. Whether or not a given quadratic differential is in the image of this map is determined by the global existence/non-existence of solutions to a certain quasi-linear PDE. It is shown that this map is not surjective. 相似文献